Superconducting and normal phases of FeSe single crystals at high pressure

被引:107
作者
Braithwaite, D. [1 ]
Salce, B. [1 ]
Lapertot, G. [1 ]
Bourdarot, F. [1 ]
Marin, C. [1 ]
Aoki, D. [1 ]
Hanfland, M. [2 ]
机构
[1] CEA, INAC SPSMS, F-38054 Grenoble, France
[2] ESRF, F-38043 Grenoble, France
关键词
Magnetic susceptibility - X ray diffraction - Lead oxide - Selenium compounds - Iron-based Superconductors - Liquefied gases - Lithium compounds - Iron compounds - Potassium compounds;
D O I
10.1088/0953-8984/21/23/232202
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
We report on the synthesis of superconducting single crystals of FeSe and their characterization by x-ray diffraction, magnetization and resistivity. We have performed ac susceptibility measurements under high pressure in a hydrostatic liquid argon medium up to 14 GPa and we find that T-C increases up to 33-36 K in all samples, but with slightly different pressure dependences on different samples. Above 12 GPa no traces of superconductivity are found in any sample. We have also performed a room temperature high pressure x-ray diffraction study up to 12 GPa on a powder sample, and we find that, between 8.5 and 12 GPa, the tetragonal PbO structure undergoes a structural transition to a hexagonal structure. This transition results in a volume decrease of about 16% and is accompanied by the appearance of an intermediate, probably orthorhombic, phase.
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页数:5
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