catena-poly[[dibromozinc(II)]-di-μ-1,4-dioxan-κ2O:O′]

被引：6

作者：

Barnes, JC ^{[1
]}

机构：

[1] Univ Dundee, Dept Chem, Dundee DD1 4HN, Scotland

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2004年 / 60卷

关键词：

D O I：

10.1107/S1600536804014072

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, [ZnBr2(C4H8O2)](n) or ZnBr2 . (dioxan), has a zigzag chain structure in which the 1,4-dioxan molecules link tetrahedrally coordinated Zn atoms. Each dioxan ring sits on a centre of symmetry. The Zn - Br distances are 2.3110( 8) and 2.3169 (8) Angstrom, and angle Br1 - Zn1 - Br2 is 124.53 (3) degrees. The Zn - O distances are 2.054 (4) and 2.043 (3) Angstrom, and angle O - Zn - O is 89.6 (15) degrees.

引用

页码：M971 / M972

页数：2

共 14 条

[1] ROLE OF 1,4-DIOXAN IN SOLID ADDUCTS OF HYDRATED METAL-HALIDES - CRYSTAL-STRUCTURES OF HEXA-AQUADICHLOROMAGNESIUM-1,4-DIOXAN(1-1), TRANS-TETRA-AQUADIBROMONICKEL(II)-1,4-DIOXAN(1-2), AND CIS-DIAQUATETRABROMOTIN(IV)-1,4-DIOXAN(1-2) [J].