Intramolecular reduction of the nitro group into phosphoraneimine mediated by a rhenium(V) complex.: Synthesis and structure of the novel phosphoraneimine oxorhenium(V) complex [ReOCl-{o-(PPh3=N) C6H4(NCH2CH2N(CH2CO2H)CH2CO2)}]

被引：4

作者：

Allali, M

Benoist, E

Gressier, M

Jaud, J

Habbadi, N

Souizi, A

Dartiguenave, M

机构：

[1] Univ Toulouse 3, Chim Inorgan Lab, F-31062 Toulouse 3, France

[2] Univ Ibn Tofail, Lab Synth Organ & Agrochim, Kenitra, Morocco

[3] CNRS, CEMES, F-31055 Toulouse 4, France

来源：

DALTON TRANSACTIONS | 2004年 / 20期

关键词：

D O I：

10.1039/b409640a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title compound was synthesised via an unexpected intramolecular reduction of a nitro group in the oxo-Re(V) coordination sphere.

引用

页码：3178 / 3180

页数：3

共 16 条

[1] Swift oxo transfer reactions of perchlorate and other substrates catalyzed by rhenium oxazoline and thiazoline complexes [J].

Abu-Omar, MM .

CHEMICAL COMMUNICATIONS, 2003, (17) :2102-2111

[2] Design and synthesis of new ethylenediamme or propylenediamine diacetic acid derivatives for Re(I) organometallic chemistry [J].

Allali, M ;

Benoist, E ;

Habbadi, N ;

Gressier, M ;

Souizi, A ;

Dartiguenave, M .

TETRAHEDRON, 2004, 60 (05) :1167-1174

[3] SIR92 - a program for automatic solution of crystal structures by direct methods [J].

ALTOMARE, A ;

CASCARANO, G ;

GIACOVAZZO, G ;

GUAGLIARDI, A ;

BURLA, MC ;

POLIDORI, G ;

CAMALLI, M .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1994, 27 :435-435

[4] Uncommon anionic dioxorhenium(V) and neutral monooxorhenium(V) mixed-ligand complexes containing heterofunctionalized phosphine ligands: Syntheses and structural characterization [J].

Bolzati, C ;

Tisato, F ;

Refosco, F ;

Bandoli, G ;

Dolmella, A .

INORGANIC CHEMISTRY, 1996, 35 (21) :6221-6229

[5] Synthesis and characterisation of oxo- and phenylimido-rhenium(V) complexes containing bidentate phosphinoenolato ligands [J].

Couillens, X ;

Gressier, M ;

Turpin, R ;

Dartiguenave, M ;

Coulais, Y ;

Beauchamp, AL .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2002, (06) :914-924

[6] Synthesis and characterization of the first mononuclear NiII phosphorane imino complex [J].

Crociani, L ;

Tisato, F ;

Refosco, F ;

Bandoli, G ;

Corain, B ;

Venanzi, LM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (12) :2973-2974

[7] Phosphoraneiminato complexes of transition metals [J].

Dehnicke, K ;

Krieger, M ;

Massa, W .

COORDINATION CHEMISTRY REVIEWS, 1999, 182 :19-65

[8] REACTIONS OF MOLYBDENUM(0) TRICARBONYL COMPLEXES WITH 8-AZIDOQUINOLINE - CRYSTAL-STRUCTURE OF THE PHOSPHINIMINE COMPLEX MO(CO)4[N(PPH3)(C9H6N)] AND EVIDENCE FOR A BENT NITRENE [J].

FOURQUET, JL ;

LEBLANC, M ;

SARAVANAMUTHU, A ;

BRUCE, MRM ;

BRUCE, AE .

INORGANIC CHEMISTRY, 1991, 30 (17) :3241-3243

[9] NOVEL IMIDO-NICKEL(II) AND PHOSPHORANE-IMIDO-NICKEL(II) COMPLEXES - CRYSTAL AND MOLECULAR-STRUCTURE OF (MU-3-NH)(MU-3-NPME3)(NICLPME3)3 [J].

KLEIN, HF ;

HALLER, S ;

KONIG, H ;

DARTIGUENAVE, M ;

DARTIGUENAVE, Y ;

MENU, MJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (12) :4673-4675

[10] RHENIUM(V) AND TECHNETIUM(V) COMPLEXES OF BIS(O-HYDROXYPHENYL)PHENYLPHOSPHINE (PO2(2-)) AND (O-HYDROXYPHENYL)DIPHENYLPHOSPHINE (PO-) LIGANDS [J].

LUO, HY ;

SETYAWATI, I ;

RETTIG, SJ ;

ORVIG, C .

INORGANIC CHEMISTRY, 1995, 34 (09) :2287-2299

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