Models for the estimation of thermodynamic properties of layered double hydroxides:: Application to the study of their anion exchange characteristics

被引：24

作者：

Bravo-Suárez, JJ

Páez-Mozo, EA

Oyama, ST

机构：

[1] Univ Ind Santander, Escuela Ingn Quim, Ctr Invest Catalisis, Bucaramanga, Colombia

[2] Virginia Polytech Inst & State Univ, Dept Chem Engn, Environm Catalysis & Nanomat Lab, Blacksburg, VA 24061 USA

[3] Univ Ind Santander, Escuela Quim, Ctr Invest Catalisis, Bucaramanga, Colombia

来源：

QUIMICA NOVA | 2004年 / 27卷 / 04期

关键词：

layered double hydroxides; thermodynamic properties; model;

D O I：

10.1590/S0100-40422004000400011

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Several models for the estimation of thermodynamic properties of layered double hydroxides (LDHs) are presented. The predicted thermodynamic quantities calculated by the proposed models agree with experimental thermodynamic data. A thermodynamic study of the anion exchange process on LDHs is also made using the described models. Tables for the prediction of monovalent anion exchange selectivities on LDHs are provided. Reasonable agreement is found between the predicted and the experimental monovalent anion exchange selectivities.

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收藏

页码：574 / 581

页数：8

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