Reactions of molecular nitrogen and triethylamine with coordinatively unsaturated iron carbonyls: Spin effects on reactions

被引：13

作者：

House, PG

Weitz, E

机构：

[1] Department of Chemistry, Northwestern University, Evanston

来源：

CHEMICAL PHYSICS LETTERS | 1997年 / 266卷 / 1-2期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/S0009-2614(96)01504-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Rate constants for the reactions of N-2 + Fe(CO)(3), N-2 + Fe(CO)(4), CO + Fe(CO)(3)(N-2), N(C2H5)(3) + Fe(CO)(3), and N(C2H5)(3) + Fe(CO)(4) are reported. The magnitudes of these rate constants are compared to rate constants for other reactions of Fe(CO)(3) and Fe(CO)(4) in the gas phase. The aforementioned reactions involving Fe(CO)(4) and Fe(CO)(3)(N-2) are anticipated to be formally spin disallowed. Factors that could influence the magnitude of the rate constants in these systems are discussed.

引用

页码：239 / 245

页数：7

共 24 条

[1]

[Anonymous], 1990, INORG CHEM

[2] AN ABINITIO STUDY OF FE(CO)1, FE(CO)5, AND CR(CO)6 [J].