Selective C-S Bond Formation via Fe-Catalyzed Allylic Substitution

被引：111

作者：

Jegelka, Markus ^{[1
]}

Plietker, Bernd ^{[1
]}

机构：

[1] Univ Stuttgart, FB Chem, Inst Organ Chem, D-70569 Stuttgart, Germany

来源：

ORGANIC LETTERS | 2009年 / 11卷 / 15期

关键词：

ASYMMETRIC-SYNTHESIS; ADDITION-REACTIONS; SULFONES; ALKYLATION; ALLYLATION; SULFIDES; COMPLEXES; URACILS;

D O I：

10.1021/ol901297s

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In contrast to the formation of C-O and C-N bonds it was only recently that the selective C-S bond formation by means of transition metal complexes moved more into the center of research. This is somewhat surprising given the fact that the sulfur atom in a functional group can possess different oxygenation levels which correspond to different chemical properties and reaction portfolios, Herein we wish to communicate a regioselective Fe-catalyzed allylic sulfonation that allows for the preparation of various chiral aryl allyl sulfones In good to excellent yields.

引用

页码：3462 / 3465

页数：4

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