A facile synthesis of thiazole-2(3H)-thiones through [hydroxy(tosyloxy)iodo]benzene

被引：19

作者：

Aggarwal, R ^{[1
]}

Pundeer, R ^{[1
]}

Kumar, V ^{[1
]}

Chaudhri, V ^{[1
]}

Singh, SP ^{[1
]}

Prakash, O ^{[1
]}

机构：

[1] Kurukshetra Univ, Chem Dept, Haryana 136119, India

来源：

SYNTHETIC COMMUNICATIONS | 2004年 / 34卷 / 14期

关键词：

D O I：

10.1081/SCC-200025631

中图分类号：

O62 [有机化学];

学科分类号：

070303 [有机化学]; 081704 [应用化学];

摘要：

A one-pot facile synthesis of thiazole-2(3H)-thiones (4) has been achieved by hypervalent iodine oxidation of ketones (1) using [hydroxy (tosyloxy)iodo] benzene, followed by the treatment of the reaction mixture with dithiocarbamate salts (3). The intermediate alpha-tosyloxy-ketones (2) have also been isolated and converted to the target compounds.

引用

页码：2659 / 2664

页数：6

共 19 条

[1]

Dains FB, 1939, J AM CHEM SOC, V61, P1830, DOI 10.1021/ja01876a055

[2]

THIAZOLETHIOLS AND THEIR DERIVATIVES [J].