The hydrophobic effect

被引：44

作者：

Paulaitis, ME ^{[1
]}

Garde, S ^{[1
]}

Ashbaugh, HS ^{[1
]}

机构：

[1] UNIV DELAWARE,DEPT CHEM ENGN,NEWARK,DE 19716

来源：

CURRENT OPINION IN COLLOID & INTERFACE SCIENCE | 1996年 / 1卷 / 03期

关键词：

D O I：

10.1016/S1359-0294(96)80137-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Computer simulation and theoretical studies have improved significantly our understanding of the connection between the structural organization of water surrounding hydrophobic solutes and anomalous thermodynamic behavior associated with the 'hydrophobic effect'. Recent studies have yielded the quantitative temperature dependence of hydrophobic interactions and the dependence of hydration free energy on solute size and shape. The success of new proximity approximations, which assume that water organization is only locally sensitive to solute structure, has encouraged the study of the hydration of complex hydrophobic solutes.

引用

页码：376 / 383

页数：8

共 27 条

[1]

ASHBAUGH A, 1996, J PHYS CHEM-US, V100, P1900

[2] SOLVATION - FROM SMALL TO MACRO MOLECULES [J].