Isolation, characterization, and interconversions of (Et(3)P)(2)Ir(C2H4)(n)Cl (n=1, 2)

被引：14

作者：

Aizenberg, M

Milstein, D

Tulip, TH

机构：

[1] WEIZMANN INST SCI, DEPT ORGAN CHEM, IL-76100 REHOVOT, ISRAEL

[2] DUPONT CO INC, CENT RES & DEV, WILMINGTON, DE 19880 USA

来源：

ORGANOMETALLICS | 1996年 / 15卷 / 19期

关键词：

D O I：

10.1021/om960385n

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The syntheses, characterization, and interconversions of (Et(3)P)(2)Ir(C2H4)(2)Cl (1) and (Et(3)P)(2)Ir(C2H4(Cl) (2) as well as the X-ray crystal structure of 1 are reported. In solution complex 1 has a stereochemically rigid trigonal-bipyramidal structure with nonrotating ethylene ligands. Formation of complex 1 from complex 2 and ethylene is thermodynamically favorable; Delta G(298) = -2.12 +/- 0.03 kcal/mol.

引用

页码：4093 / 4095

页数：3

共 23 条

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