An investigation of thermally prepared electrodes for oxygen reduction in alkaline solution

被引：27

作者：

Chang, CC ^{[1
]}

Wen, TC ^{[1
]}

机构：

[1] NATL CHENG KUNG UNIV,DEPT CHEM ENGN,TAINAN 70101,TAIWAN

来源：

MATERIALS CHEMISTRY AND PHYSICS | 1997年 / 47卷 / 2-3期

关键词：

thermally prepared electrodes; electrocatalytic activity; electrocatalytic stability; potentiostatic polarization; cyclic voltammetry;

D O I：

10.1016/S0254-0584(97)80052-1

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The electrocatalytic activity and stability of various thermally prepared electrodes (of metal species Pd, Pt, Ir, Co, Ru, and Ni) for oxygen reduction in 1 M KOH are investigated. Electrocatalytic activity is elucidated by potentiostatic polarization and galvanostatic electrolysis. Tafel slopes, exchange current densities and onset potentials are derived from potentiostatic polarization and are used to explain the different processes of oxygen reduction on various electrodes. In order to evaluate electrode stability, CV, SEM and XRD are used to test for changes in electrode surface.

引用

页码：203 / 210

页数：8

共 35 条

[1] OXYGEN REDUCTION ON A MODIFIED RUTHENIUM ELECTRODE
ANASTASIJEVIC, N
DIMITRIJEVIC, ZM
ADZIC, RR
[J]. ELECTROCHIMICA ACTA, 1992, 37 (03) : 457 - 464
[2] OXYGEN REDUCTION ON A RUTHENIUM ELECTRODE IN ALKALINE ELECTROLYTES
ANASTASIJEVIC, NA
DIMITRIJEVIC, ZM
ADZIC, RR
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1986, 199 (02) : 351 - 364
[3] OXYGEN REDUCTION ON STAINLESS-STEEL
BABIC, R
METIKOSHUKOVIC, M
[J]. JOURNAL OF APPLIED ELECTROCHEMISTRY, 1993, 23 (04) : 352 - 357
[4] THE REDUCTION OF OXYGEN ON TITANIUM-OXIDE ELECTRODES
BAEZ, VB
GRAVES, JE
PLETCHER, D
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1992, 340 (1-2): : 273 - 286
[5] ELECTROCHEMICAL OXYGEN REDUCTION ON OXIDE CATALYSTS
BAGOTZKY, VS
SHUMILOVA, NA
KHRUSHCHEVA, EI
[J]. ELECTROCHIMICA ACTA, 1976, 21 (11) : 919 - 924
[6] BURKE LD, 1994, J APPL ELECTROCHEM, V24, P30, DOI 10.1007/BF00243326
[7] CHANG CC, 1995, UNPUB J ELECTROCHEM
[8] MECHANISM OF THE MEDIATED REDUCTION OF HYDROGEN-PEROXIDE AT AN ELECTRODE MODIFIED WITH A FILM CONTAINING A BASIC FORM OF IRIDIUM OXIDE
COX, JA
JAWORSKI, RK
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1990, 281 (1-2): : 163 - 170
[9] MECHANISM OF OXYGEN REDUCTION AT PLATINUM IN ALKALINE SOLUTIONS WITH SPECIAL REFERENCE TO H2O2
DAMJANOVIC, A
GENSHAW, MA
BOCKRIS, JO
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1967, 114 (11) : 1107 - +
[10] ELECTROCHEMISTRY OF RUTHENATES .1. OXYGEN REDUCTION ON PYROCHLORE RUTHENATES
EGDELL, RG
GOODENOUGH, JB
HAMNETT, A
NAISH, CC
[J]. JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1983, 79 : 893 - 912

← 1 2 3 4 →