Water-soluble oligomer dimers based on paracyclophane: A new optical platform for fluorescent sensor applications

被引：38

作者：

Hong, JW

Gaylord, BS

Bazan, GC ^{[1
]}

机构：

[1] Univ Calif Santa Barbara, Dept Chem, Santa Barbara, CA 93106 USA

[2] Univ Calif Santa Barbara, Dept Mat, Santa Barbara, CA 93106 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2002年 / 124卷 / 40期

关键词：

D O I：

10.1021/ja027170r

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Water soluble paracyclophane chromophore dimers provide optical reporters that show little sensitivity to surfactants and thus are ideal for biosensor design. Strong intramolecular delocalization circumvents complications from intermolecular delocalization in spontaneously formed aggregates. The synthesis of 2 involves a novel TBAT deprotection/butane sultone ring-opening sequence, which should be general for the preparation of water-soluble conjugated oligomers and polymers. Copyright © 2002 American Chemical Society.

引用

页码：11868 / 11869

页数：2

共 23 条

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