Catalytic enantioselective deprotonation of meso-epoxides utilising homochiral bis-lithium amide bases

被引：46

作者：

Tierney, JP ^{[1
]}

Alexakis, A ^{[1
]}

Mangeney, P ^{[1
]}

机构：

[1] UNIV PARIS 06,URA 473 CNRS,LAB CHIM ORGANOELEMENTS,F-75252 PARIS 05,FRANCE

来源：

TETRAHEDRON-ASYMMETRY | 1997年 / 8卷 / 07期

关键词：

D O I：

10.1016/S0957-4166(97)00084-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

(R)-2-Cyclohexen-1-ol and (R)-2-cyclooctene-1-ol have been prepared in very good ee using R,R-homochiral bis-lithium amide bases derived from homochiral C-2 symmetric diamines. (R)-2-Cyclohexen-1-ol has been synthesized in good ee utilising catalytic homochiral bis-lithium amide in the presence of n-butyl lithium. (C) 1997 Elsevier Science Ltd.

引用

页码：1019 / 1022

页数：4

共 28 条

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