Reactivity of the solid electrolyte interface on carbon electrodes at elevated temperatures

被引：105

作者：

Zheng, T ^{[1
]}

Gozdz, AS ^{[1
]}

Amatucci, GG ^{[1
]}

机构：

[1] Telcordia Technol, Red Bank, NJ 07701 USA

来源：

JOURNAL OF THE ELECTROCHEMICAL SOCIETY | 1999年 / 146卷 / 11期

关键词：

D O I：

10.1149/1.1392585

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The stability and reformation of solid electrolyte interfaces (SEIs) on carbon electrodes during storage at elevated temperatures were studied. The capacity change observed for carbon samples after storage at elevated temperatures is attributed to the instability of the SEI layer in the liquid electrolyte. The capacity change was found to correlate well with the specific surface area of graphite. (C) Telcordia Technologies. The Electrochemical Society. S0013-4651(99)04-006-9.

引用

收藏

页码：4014 / 4018

页数：5

相关论文

共 9 条

[1] THE STUDY OF ELECTROLYTE-SOLUTIONS BASED ON ETHYLENE AND DIETHYL CARBONATES FOR RECHARGEABLE LI BATTERIES .1. LI METAL ANODES [J].

AURBACH, D ;

ZABAN, A ;

SCHECHTER, A ;

EINELI, Y ;

ZINIGRAD, E ;

MARKOVSKY, B .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1995, 142 (09) :2873-2882

[2]

BIENSAN P, 1996, P JOURN ET ACC LITH

[3]

Du Pasquier A, 1998, J ELECTROCHEM SOC, V145, P472

[4] STUDIES OF LITHIUM INTERCALATION INTO CARBONS USING NONAQUEOUS ELECTROCHEMICAL-CELLS [J].

FONG, R ;

VONSACKEN, U ;

DAHN, JR .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1990, 137 (07) :2009-2013

[5]

JEAN M, 1996, INT M LITH BATT JUN

[6] CARBON-FIBER AS A NEGATIVE ELECTRODE IN LITHIUM SECONDARY CELLS [J].

KANNO, R ;

KAWAMOTO, Y ;

TAKEDA, Y ;

OHASHI, S ;

IMANISHI, N ;

YAMAMOTO, O .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1992, 139 (12) :3397-3404

[7] THE ELECTROCHEMICAL-BEHAVIOR OF ALKALI AND ALKALINE-EARTH METALS IN NON-AQUEOUS BATTERY SYSTEMS - THE SOLID ELECTROLYTE INTERPHASE MODEL [J].

PELED, E .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1979, 126 (12) :2047-2051

[8] Unique effect of mechanical milling on the lithium intercalation properties of different carbons [J].

SalverDisma, F ;

Lenain, C ;

Beaudoin, B ;

Aymard, L ;

Tarascon, JM .

SOLID STATE IONICS, 1997, 98 (3-4) :145-158

[9] Graphites for lithium-ion cells: The correlation of the first-cycle charge loss with the Brunauer-Emmett-Teller surface area [J].

Winter, M ;

Novak, P ;

Monnier, A .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1998, 145 (02) :428-436