Cyclic carbonate synthesis from supercritical carbon dioxide and epoxide over lanthanide oxychloride

被引：245

作者：

Yasuda, H ^{[1
]}

He, LN ^{[1
]}

Sakakura, T ^{[1
]}

机构：

[1] AIST, Tsukuba, Ibaraki 3058565, Japan

来源：

JOURNAL OF CATALYSIS | 2002年 / 209卷 / 02期

关键词：

propylene carbonate; propylene oxide; supercritical carbon dioxide; lanthanide oxychloride;

D O I：

10.1006/jcat.2002.3662

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Lanthanide oxychloride, especially SmOCl, is an efficient solid catalyst for propylene carbonate synthesis from supercritical CO2 and propylene oxide. The process requires no additional organic solvents and the product is automatically separated out from the CO2 phase. (C) 2002 Elsevier Science (USA).

引用

页码：547 / 550

页数：4

共 31 条

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[2]

Aresta M, 1997, CHEMTECH, V27, P32

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