Elaboration of poly(ε-caprolactone)-g-TiNbO5 nanocomposites via in situ metal complex initiated Intercalative polymerization

被引:7
作者
Bruzaud, S
Carpentier, JF
Grohens, Y
机构
[1] Univ Bretagne Sud, Lab Polymeres & Proc, F-56321 Lorient, France
[2] Univ Rennes 1, CNRS, UMR 6509, Inst Chim,Lab Organomet & Catalyse, F-35042 Rennes, France
关键词
nanocomposites; nanolayers; poly(epsilon-caprolactone)-g-TiNbO5 materials; ring-opening polymerization;
D O I
10.1002/mame.200300346
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The preparation of poly(epsilon-caprolactene)-g-TiNbO5 nanocomposites via in situ intercalative polymerization of epsilon-caprolactone initiated by an aluminium complex is described. These nanocomposites were obtained in the presence of HTiNbO5 mineral pre-treated by AlMe3, but non-modified by tetraalkylammonium cations. These hybrid materials obtained have been characterized by Fourier transform infrared absorption spectroscopy, wide-angle X-ray scattering, scanning electron microscopy, and dynamic mechanical analysis. Layered structure delamination and homogenous distribution of mineral lamellae in the poly-(epsilon-caprolactone) (PCL) is figured out and strong improvement of the mechanical properties achieved. The storage modulus of the nanocomposites is enchanced a compared to pure PCL and increases monotonously with the amount of the filler in the range 3 to 10 wt.%.
引用
收藏
页码:531 / 538
页数:8
相关论文
共 22 条
[1]   Polymer-layered silicate nanocomposites: Preparation, properties and uses of a new class of materials [J].
Alexandre, Michael ;
Dubois, Philippe .
Materials Science and Engineering: R: Reports, 2000, 28 (1-2) :1-63
[2]   Polyethylene-layered silicate nanocomposites prepared by the polymerization-filling technique:: synthesis and mechanical properties [J].
Alexandre, M ;
Dubois, P ;
Sun, T ;
Garces, JM ;
Jérôme, R .
POLYMER, 2002, 43 (08) :2123-2132
[3]   Modeling the barrier properties of polymer-layered silicate nanocomposites [J].
Bharadwaj, RK .
MACROMOLECULES, 2001, 34 (26) :9189-9192
[4]   Polysiloxane-g-TiNbO5 nanocomposites:: Synthesis via in situ intercalative polymerization and preliminary characterization [J].
Bruzaud, S ;
Levesque, G .
CHEMISTRY OF MATERIALS, 2002, 14 (05) :2421-2426
[5]   Nanocomposites by melt intercalation based on polycaprolactone and organoclay [J].
Di, YW ;
Iannace, S ;
Di Maio, E ;
Nicolais, L .
JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 2003, 41 (07) :670-678
[6]   Polymer-clay nanocomposites: exfoliation of organophilic montmorillonite nanolayers in polystyrene [J].
Fu, X ;
Qutubuddin, S .
POLYMER, 2001, 42 (02) :807-813
[7]  
Giannelis EP, 1999, ADV POLYM SCI, V138, P107
[8]   Influence of clay exfoliation on the physical properties of montmorillonite/polyethylene composites [J].
Gopakumar, TG ;
Lee, JA ;
Kontopoulou, M ;
Parent, JS .
POLYMER, 2002, 43 (20) :5483-5491
[9]   ORGANIC INTERCALATION ON LAYERED COMPOUND KTINBO5 [J].
KIKKAWA, S ;
KOIZUMI, M .
MATERIALS RESEARCH BULLETIN, 1980, 15 (04) :533-539
[10]   Poly(ε-caprolactone)/clay nanocomposites prepared by melt intercalation:: mechanical, thermal and rheological properties [J].
Lepoittevin, B ;
Devalckenaere, M ;
Pantoustier, N ;
Alexandre, M ;
Kubies, D ;
Calberg, C ;
Jérôme, R ;
Dubois, P .
POLYMER, 2002, 43 (14) :4017-4023