Evidence for molecular assembly in hydrotalcites

被引:9
作者
Frost, RL [1 ]
Martens, WN [1 ]
Duong, L [1 ]
Kloprogge, JT [1 ]
机构
[1] Queensland Univ Technol, Ctr Instrumental & Dev Chem, Brisbane, Qld 4001, Australia
关键词
D O I
10.1023/A:1016542700574
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The unique structure of hydrotalcites was explored using an infrared spectroscopy. The hydroxyl-stretching of CuOH, ZnOH and AlOH were identified by unique band positions. Evidence was obtained that water is highly structured within the hydrotalcite layers and is in a regular structure such that the water is hydrogen bonded to the carbonate anion and to the cationic hydroxyl surface.
引用
收藏
页码:1237 / 1239
页数:3
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