An examination of the gelation of methacrylate type crosslinking agents for the preparation of polymer monolith with 3D ordered network structures

被引：4

作者：

Aoki, H

Kubo, T

Watabe, Y

Tanaka, N

Norisuye, T

Hosoya, K ^{[1
]}

Shimbo, K

机构：

[1] Kyoto Inst Technol, Dept Polymer Sci, Sakyo Ku, Kyoto 6068585, Japan

[2] Showa Denko Co Ltd, Special Chem Div, Prod & Technol Control Dept, Kawasaki Ku, Kawasaki, Kanagawa 2100867, Japan

来源：

CHEMISTRY LETTERS | 2004年 / 33卷 / 09期

关键词：

D O I：

10.1246/cl.2004.1134

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The gelation of dimethacrylate type crosslinking agents was studied from the perspective of formation of ordered three dimensional (3D) network structures. Dynamic light scattering (DLS) data showed that the gelation of hydrophilic crosslinking agents having OH groups such as glycerol dimethacrylate (GDMA) was enhanced through hydrogen bonding in a hydrophobic solvent system such as toluene, which afforded more ordered 3D structures.

引用

页码：1134 / 1135

页数：2

共 7 条

[1]

Frechet J. M. J., 1995, U.S. Patent, Patent No. [5,453,185, 5453185]

[2] Preparation strategy for uniformly sized, polymer-based HPLC packing materials having practically acceptable column efficiency. 1. Copolymerization technique [J].