A new dioxotetraamine ligand appended with fluorenyl and its copper(II) complex. Synthesis, crystal structure and solution behavior

被引：15

作者：

Jiang, LJ

Luo, QH ^{[1
]}

Duan, CY

Shen, MC

Hu, HW

Liu, YJ

机构：

[1] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China

[2] Peking Univ, State Key Lab Rare Earth Mat Chem & Applicat, Beijing 100871, Peoples R China

来源：

INORGANICA CHIMICA ACTA | 1999年 / 295卷 / 01期

基金：

中国国家自然科学基金;

关键词：

crystal structures; fluorescence; fluorenyl complexes; copper complexes;

D O I：

10.1016/S0020-1693(99)00305-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new dioxotetraamine ligand 6-(9-fluorenyl)-1,4,8,11-tetraazaundecane-5,7-dione (L) and its copper(II) complex have been synthesized. Detailed studies have been made on solution chemistry of Cu(II), Ni(II) and Co(II) complexes of the ligand by pH-potentiometric and fluorimetric titration as well as cyclic voltammetry. The coordination of Cu2+ and Ni(2+)quenches the fluorescence of fluorenyl in the ligand through an electron transfer mechanism. The crystal structure of [Cu(H-2L)] was determined. (C) 1999 Elsevier Science S.A. All rights reserved.

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页码：48 / 55

页数：8

相关论文

共 37 条

[1] A ditopic tetradentate pyridyl amine ligand containing an anthracene fragment:: fluorescence intensity and 'closed' vs.'open' species formation in the presence of Cu2+, as a function of pH [J].

Amendola, V ;

Fabbrizzi, L ;

Pallavicini, P ;

Parodi, L ;

Perotti, A .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1998, (12) :2053-2057

[2] MOLECULAR FLUORESCENT SIGNALING WITH FLUOR SPACER RECEPTOR SYSTEMS - APPROACHES TO SENSING AND SWITCHING DEVICES VIA SUPRAMOLECULAR PHOTOPHYSICS [J].

BISSELL, RA ;

DE SILVA, AP ;

GUNARATNE, HQN ;

LYNCH, PLM ;

MAGUIRE, GEM ;

SANDANAYAKE, KRAS .

CHEMICAL SOCIETY REVIEWS, 1992, 21 (03) :187-195

[3]

Bu XH, 1998, J CHEM SOC DALTON, P2247

[4] NEW 1,4,7,10-TETRAAZACYCLOTRIDECANE-11,13-DIONE LIGANDS APPENDED WITH ADDITIONAL DONOR(S) 8-METHYLQUINOLINE(S) - CRYSTAL-STRUCTURES AND CHARACTERIZATION OF THEIR COPPER(II) COMPLEXES [J].

BU, XH ;

AN, DL ;

CHEN, YT ;

SHIONOYA, M ;

KIMURA, E .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1995, (13) :2289-2295

[5] Synthesis, crystal structure and properties of the copper(II) complex of a new dioxocyclam appended with two 8-methylquinolines as additional donor pendants (dioxocyclam=1,4,8,11-tetraazacyclotetradecane-5,7-dione) [J].

Bu, XH ;

Zhang, ZH ;

An, DL ;

Chen, YT ;

Shionoya, M ;

Kimura, E .

INORGANICA CHIMICA ACTA, 1996, 249 (01) :125-130

[6]

Bu XH, 1998, J CHEM SOC DALTON, P433

[7] AN ANTHRACENE-BASED FLUORESCENT SENSOR FOR TRANSITION-METAL IONS [J].

FABBRIZZI, L ;

LICCHELLI, M ;

PALLAVICINI, P ;

PEROTTI, A ;

SACCHI, D .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1994, 33 (19) :1975-1977

[8] A fluorescent cage for anion sensing in aqueous solution [J].

Fabbrizzi, L ;

Faravelli, I ;

Francese, G ;

Licchelli, M ;

Perotti, A ;

Taglietti, A .

CHEMICAL COMMUNICATIONS, 1998, (09) :971-972

[9] Transition metal (II)/(III), Eu(III), and Tb(III) ions induced molecular photonic OR gates using trianthryl cryptands of varying cavity dimension [J].

Ghosh, P ;

Bharadwaj, PK ;

Roy, J ;

Ghosh, S .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (49) :11903-11909

[10] Ni(II), Cu(II), and Zn(II) cryptate-enhanced fluorescence of a trianthrylcryptand: A potential molecular photonic OR operator [J].

Ghosh, P ;

Bharadwaj, PK ;

Mandal, S ;

Ghosh, S .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (06) :1553-1554

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