Geometrical explanation and scaling of dynamical heterogeneities in glass forming systems

被引:383
作者
Garrahan, JP
Chandler, D
机构
[1] Univ Oxford, Oxford OX1 3PN, England
[2] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA
关键词
D O I
10.1103/PhysRevLett.89.035704
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
We show how dynamical heterogeneities in glass forming systems emerge as a consequence of the existence of dynamical constraints, and we offer an interpretation of the glass transition as an entropy crisis in trajectory space (space-time) rather than in configuration space. To illustrate our general ideas, we analyze the one-dimensional (d=1) Fredrickson-Andersen and East models. Dynamics of such dynamically constrained systems are shown to be isomorphic to the statics of (d+1 )-dimensional dense mixtures of polydisperse noninterpenetrating domains. The domains coincide with arrested regions in trajectory space.
引用
收藏
页码:357041 / 357044
页数:4
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