Synthesis of 1-tert-butoxy-2-propanol (PGTBE) from propylene glycol and isobutene in a packed trickle-bed reactor on acid catalysts

被引：7

作者：

Alcántara, R ^{[1
]}

Canoira, L ^{[1
]}

Fernández-Martín, C ^{[1
]}

Franco, MJ ^{[1
]}

Martinez-Silva, JI ^{[1
]}

Navarro, A ^{[1
]}

机构：

[1] Univ Politecn Madrid, Dept Chem Engn & Fuels, Sch Mines, Madrid 28003, Spain

来源：

REACTIVE & FUNCTIONAL POLYMERS | 2000年 / 43卷 / 1-2期

关键词：

1-tert-butoxy-2-propanol; montmorillonite; Amberlyst; 15; packed trickle-bed reactor; antiknock properties;

D O I：

10.1016/S1381-5148(99)00008-5

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

1-tert-Butoxy-2-propanol has been synthesized from propylene glycol and isobutene over two solid acid catalysts, montmorillonite and Amberlyst 15, in a packed trickle-bed reactor operating under different experimental conditions, and its antiknock properties as an oxygenate gasoline additive have been evaluated. The reaction on Amberlyst 15 fitted first-order kinetics for isobutene (k' = 0.37 h(-1)) for a molar ratio propylene glycol to isobutene of one. (C) 2000 Elsevier Science B.V. All rights reserved.

引用

页码：97 / 104

页数：8

共 13 条

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