2,6-diphenylbenzo[1,2-b:4,5-b′]dichalcogenophenes:: a new class of high-performance semiconductors for organic field-effect transistors

被引:222
作者
Takimiya, K
Kunugi, Y
Konda, Y
Niihara, N
Otsubo, T
机构
[1] Hiroshima Univ, Grad Sch Engn, Higashihiroshima 7398527, Japan
[2] Hiroshima Univ, Fac Integrated Arts & Sci, Higashihiroshima 7398521, Japan
关键词
D O I
10.1021/ja0496930
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
2,6-Diphenylbenzo[1,2-b:4,5-b′]dichalcogenophenes including thiophene, selenophene, and tellurophene analogues as organic semiconductors for field-effect transistors were effectively synthesized in three steps from commercially available 1,4-dibromobenzene. All three benzodichalcogenophenes acted as good p-type semiconductors, and particularly the selenophene analogue, 2,6-diphenylbenzo[1,2-b:4,5-b′]diselenophene, showed high FET mobility of 0.17 cm2 V-1 s-1. Copyright © 2003 American Chemical Society.
引用
收藏
页码:5084 / 5085
页数:2
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