Metal-catalyzed living radical polymerization: Discovery and developments

被引：121

作者：

Kamigaito, M

Ando, T

Sawamoto, M

机构：

[1] Nagoya Univ, Grad Sch Engn, Dept Appl Chem, Chikusa Ku, Nagoya, Aichi 4648603, Japan

[2] Kyoto Univ, Grad Sch Engn, Dept Polymer Chem, Nishikyo Ku, Kyoto 6158510, Japan

来源：

CHEMICAL RECORD | 2004年 / 4卷 / 03期

关键词：

living polymerization; radical polymerization; ruthenium; iron; block copolymers;

D O I：

10.1002/tcr.20011

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Control of radical polymerization has been one of the most challenging frontiers in polymerization chemistry. This review presents the discovery of metal-catalyzed living radical polymerization and recent developments in the evolution of catalysts in terms of versatility and activity, scope of monomers, controlled polymerization in water, catalyst removal, and precision synthesis of well-controlled polymers such as random, block, end-functionalized, and star polymers. (C) 2004 The Japan Chemical Journal Forum and Wiley Periodicals, Inc.

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页码：159 / 175

页数：17

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