Infrared multiphoton excitation, dissociation and ionization of C-60

被引：31

作者：

Hippler, M

Quack, M

Schwarz, R

Seyfang, G

Matt, S

Mark, T

机构：

[1] ETH ZURICH, PHYS CHEM LAB, CH-8092 ZURICH, SWITZERLAND

[2] UNIV INNSBRUCK, INST IONENPHYS, A-6020 INNSBRUCK, AUSTRIA

来源：

CHEMICAL PHYSICS LETTERS | 1997年 / 278卷 / 1-3期

基金：

奥地利科学基金会;

关键词：

D O I：

10.1016/S0009-2614(97)00861-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We report the observation of mid-infrared multiphoton excitation, dissociation, and ionization of C-60 by shaped CO2 laser pulses. The results are interpreted in the framework of the general statistical theory of infrared laser chemistry, adding some simple model assumptions. The observations on intensity-and fluence-dependent fragment ion distributions are consistent with a mechanism of vibrational preionization from energies exceeding the threshold for ionization by about a factor of 8. (C) 1997 Elsevier Science B.V.

引用

页码：111 / 120

页数：10

共 35 条

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