The conductive polyaniline/poly(ethylene terephthalate) composite fabrics

被引:45
作者
Kutanis, S.
Karakisla, M.
Akbulut, U.
Sacak, M.
机构
[1] Ankara Univ, Fac Sci, Dept Chem, TR-06100 Ankara, Turkey
[2] Middle E Tech Univ, Fac Sci, Dept Chem, TR-06531 Ankara, Turkey
关键词
fabrics/textiles; mechanical properties; strength;
D O I
10.1016/j.compositesa.2006.02.008
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Conductive composite fabrics were prepared by chemical polymerization of aniline on poly(ethylene terephthalate) (PET) fabrics in the aqueous hydrochloride acid solutions using potassium dichromate as the oxidant. The effect of the polymerization conditions such as temperature, oxidant, aniline and hydrochloride acid concentrations was investigated on the electrical surface resistance and polyaniline (PAn) content of PAn/PET composite fabrics. The maximum PAn content and the lower electrical resistance of composite fabrics were observed at the HCl concentrations of 0.25 M and 1.5 M, respectively. The electrical surface resistance of the PAn/PET composite fabrics was decreased under vacuum five-fold more than the ones kept under in air. The properties of PAn/PET composite fabrics such as density, diameter and moisture regain were also investigated in comparison with the those of pure PET. The conductive composite fabrics were characterized by surface resistance, FTIR and TGA techniques. (c) 2006 Elsevier Ltd. All rights reserved.
引用
收藏
页码:609 / 614
页数:6
相关论文
共 38 条
[1]  
Bhadani SN, 1997, J APPL POLYM SCI, V64, P1073
[2]   AN ELECTRICALLY-CONDUCTIVE COMPOSITE PREPARED BY ELECTROCHEMICAL POLYMERIZATION OF PYRROLE INTO POLYURETHANE [J].
BI, XT ;
PEI, QB .
SYNTHETIC METALS, 1987, 22 (02) :145-156
[3]   Enhancement of the thermal stability of chemically synthesized polypyrrole [J].
Child, AD ;
Kuhn, HH .
SYNTHETIC METALS, 1997, 84 (1-3) :141-142
[4]   Electrically conducting high-strength aramid composite fibres prepared by vapour-phase polymerization of pyrrole [J].
Cho, JW ;
Jung, H .
JOURNAL OF MATERIALS SCIENCE, 1997, 32 (20) :5371-5376
[5]   POLYANILINE - A HISTORICAL SURVEY [J].
GENIES, EM ;
BOYLE, A ;
LAPKOWSKI, M ;
TSINTAVIS, C .
SYNTHETIC METALS, 1990, 36 (02) :139-182
[6]   Conducting polymers prepared by oxidative polymerization: Polyaniline [J].
Gospodinova, N ;
Terlemezyan, L .
PROGRESS IN POLYMER SCIENCE, 1998, 23 (08) :1443-1484
[7]  
GREGORY RV, 1989, SYNTHETIC MET, V28, pC823, DOI 10.1016/0379-6779(89)90610-3
[8]   ANODIC-OXIDATION PATHWAYS OF N-ALKYLANILINES [J].
HAND, RL ;
NELSON, RF .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1974, 96 (03) :850-860
[9]   SURFACE AND ADHESION PROPERTIES OF POLYPYRROLE-COATED TEXTILES [J].
HEISEY, CL ;
WIGHTMAN, JP ;
PITTMAN, EH ;
KUHN, HH .
TEXTILE RESEARCH JOURNAL, 1993, 63 (05) :247-256
[10]   POLYANILINE/PPD-T FIBERS [J].
HSU, CH ;
VACASEGONDS, P ;
EPSTEIN, AJ .
SYNTHETIC METALS, 1991, 41 (03) :1005-1008