Superdiffusive-like motion of colloidal nanorods

被引:12
作者
Campos, Daniel [1 ,2 ]
Mendez, Vicenc [2 ]
机构
[1] Univ Manchester, Sch Math, Dept Appl Math, Manchester M60 1QD, Lancs, England
[2] Univ Autonoma Barcelona, Dept Fis, Grp Fis Estadist, E-08193 Barcelona, Spain
关键词
colloids; diffusion; gold alloys; monolayers; nanostructured materials; platinum alloys; ENHANCED DIFFUSION;
D O I
10.1063/1.3102096
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070305 [高分子化学与物理];
摘要
In recent experiments, the temporal average C(t) of the mean square displacement for nanorods moving through a chemical monolayer was explored. The results showed a scaling C(t)similar to t(1.6), which suggest the existence of superdiffusive motion for these particles. In this paper, we interpret these results by means of a continuous-time random walk (CTRW) model from which we can reproduce the exponent 1.6 and the curve C(t) versus time found in the experiments. We show that the behavior observed arises as a consequence of the superposition of different transport mechanisms: directional propulsion plus translational and rotational diffusion. Our model reveals that this superdiffusive-like scaling may also be found in other systems as in chemotactic biological motion, provided that the characteristic times for translational and rotational diffusions are very different.
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页数:4
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