A rotaxane of a 1,1′-disubstituted ferrocene and β-cyclodextrin

被引：28

作者：

Skinner, PJ ^{[1
]}

Blair, S ^{[1
]}

Kataky, R ^{[1
]}

Parker, D ^{[1
]}

机构：

[1] Univ Durham, Dept Chem, Durham DH1 3LE, England

来源：

NEW JOURNAL OF CHEMISTRY | 2000年 / 24卷 / 05期

关键词：

D O I：

10.1039/b000438n

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis is reported of the first rotaxane involving a bound ferrocenyl moiety and beta-cyclodextrin; cyclodextrin groups are used as stoppers; intermediate 1:1 adduct formation in d(8)-THF was monitored by HR-DOSY methods (K-d = 25 mM, 293 K) and the product rotaxane, isolated in 11% yield, has been characterised by MMR, CD and MALDI-TOF MS.

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页码：265 / 268

页数：4

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