Perfluoroorganosilver(I) compounds

被引：53

作者：

Tyrra, W ^{[1
]}

Naumann, D ^{[1
]}

机构：

[1] Univ Cologne, Inst Anorgan Chem, D-50939 Cologne, Germany

来源：

JOURNAL OF FLUORINE CHEMISTRY | 2004年 / 125卷 / 06期

关键词：

silver; perfluoroorgano; synthesis; oxidation;

D O I：

10.1016/j.jfluchem.2004.01.032

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A survey of different methods to prepare perfluoroorganosilver(I) compounds is given. The reaction of silver(l) fluoride with trimethyl(perfluoroorgano)silanes offers a new convenient method for the syntheses of these compounds. The formation of bis(perfluoroorgano)argentates(l) is discussed and the crystal structure of [PNP][Ag(CF3)Cl] is described. Many examples of the application of perfluoroorganosilver(l) compounds as excellent synthons in nucleophilic substitutions and oxidative perfluoroorganylations are given. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：823 / 830

页数：8

共 50 条

[1]

BANKS RE, 1970, TETRAHEDRON LETT, P5212

[2] POLYFLUOROAROMATIC DERIVATIVES OF METAL-CARBONYLS .9. REACTIONS OF PENTAFLUOROPHENYLSILVER(I) WITH SOME TRANSITION-METAL HALOGENO-COMPLEXES - OXIDATIVE-ADDITION REACTIONS OF COMPLEX CARBONYL-(PENTAFLUOROPHENYL)BIS(TRIPHENYLPHOSPHINE)IRIDIUM(I) [J].

BENNETT, RL ;

BRUCE, MI ;

GARDNER, RCF .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1973, (23) :2653-2657

[3]

BENNETT RL, 1973, J FLUORINE CHEM, V2, P447

[4] TRANSFER OF PERFLUOROALKYL GROUPS BETWEEN METALS - PREPARATION OF THE ANIONIC PERFLUOROALKYL METAL-COMPLEX AG[CF(CF3)2]2- [J].

BURCH, RR ;

CALABRESE, JC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (17) :5359-5360

[5] The Iowa connection [J].

Burton, DJ .

JOURNAL OF FLUORINE CHEMISTRY, 1999, 100 (1-2) :177-199

[6] FLUORINATED ORGANOMETALLICS - PERFLUOROALKYL AND FUNCTIONALIZED PERFLUOROALKYL ORGANOMETALLIC REAGENTS IN ORGANIC-SYNTHESIS [J].

BURTON, DJ ;

YANG, ZY .

TETRAHEDRON, 1992, 48 (02) :189-275

[7]

CAENERS B, 1990, THESIS DORTMUND

[8] Synthesis, characterization and chemistry of bis-(pentafluorophenyl)boryl ferrocene [J].

Carpenter, BE ;

Piers, WE ;

Parvez, M ;

Yap, GPA ;

Rettig, SJ .

CANADIAN JOURNAL OF CHEMISTRY, 2001, 79 (5-6) :857-867

[9] AROMATIC POLYFLUORO-COMPOUNDS .31. SYNTHESIS AND REACTIONS OF SOME HALOGENOMETHYLPENTAFLUOROPHENYLMETHANOLS AND ROUTES TO SOME PENTAFLUOROPHENYLACETYLENES [J].

COE, PL ;

PLEVEY, RG ;

TATLOW, JC .

JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC, 1966, (06) :597-&

[10] NON-OXO CHEMISTRY OF MANGANESE IN HIGH OXIDATION-STATES .1. MONONUCLEAR TERT-BUTYLIMIDO COMPOUNDS OF MANGANESE-(VII) AND MANGANESE-(VI) [J].

DANOPOULOS, AA ;

WILKINSON, G ;

SWEET, TKN ;

HURSTHOUSE, MB .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1994, (07) :1037-1049

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