Vanadium complexes of the N(CH2CH2S)(3)(3-)-ligand with co-ligands relevant to nitrogen fixation processes

被引：26

作者：

Davies, SC

Hughes, DL

Janas, Z

Jerzykiewicz, L

Richards, RL

Sanders, JR

Sobota, P

机构：

[1] JOHN INNES CTR PLANT SCI RES, NITROGEN FIXAT LAB, NORWICH NR4 7UH, NORFOLK, ENGLAND

[2] WROCLAW B BEIRUT UNIV, FAC CHEM, PL-50383 WROCLAW, POLAND

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 14期

关键词：

D O I：

10.1039/a702885g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Vanadium(III) and vanadium(V) complexes of the tris(2-thiolatoethyl)amine ligand L3- containing hydrazine, hydrazide, imide, ammine, cyanide and isocyanide ligands are synthesised; the complexes [V(NH3)L] and [V(NNMe2)L] have been structurally characterised.

引用

页码：1261 / 1262

页数：2

共 13 条

[1] THE CRYSTAL AND MOLECULAR-STRUCTURE OF BIS(1-METHYL-1-PHENYLHYDRAZINE)DICHLORO-(1-METHYL-1-PHENYLHYDRAZIDO(2-))VANADIUM(V) CHLORIDE, A COMPLEX CONTAINING 2 SIDE-ON-CO-ORDINATED HYDRAZINE MOLECULES
BULTITUDE, J
LARKWORTHY, LF
POVEY, DC
SMITH, GW
DILWORTH, JR
LEIGHT, GJ
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (24) : 1748 - 1750
[2] Synthesis and X-ray crystal structures of imido and isodiazene complexes of vanadium, niobium and tantalum
Danopoulos, AA
HayMotherwell, RS
Wilkinson, G
Sweet, TKN
Hursthouse, MB
[J]. POLYHEDRON, 1997, 16 (07) : 1081 - 1088
[3] THE MO-BASED, V-BASED, AND FE-BASED NITROGENASE SYSTEMS OF AZOTOBACTER
EADY, RR
[J]. ADVANCES IN INORGANIC CHEMISTRY, 1991, 36 : 77 - 102
[4] THE CHEMISTRY OF NITROGEN-FIXATION AND MODELS FOR THE REACTIONS OF NITROGENASE
HENDERSON, RA
LEIGH, GJ
PICKETT, CJ
[J]. ADVANCES IN INORGANIC CHEMISTRY, 1983, 27 : 197 - 292
[5] HENDERSON RA, UNPUB
[6] CATALYTIC REDUCTION OF HYDRAZINE TO AMMONIA BY THE VFE3S4 CUBANES - FURTHER EVIDENCE FOR THE DIRECT INVOLVEMENT OF THE HETEROMETAL IN THE REDUCTION OF NITROGENASE SUBSTRATES AND POSSIBLE RELEVANCE TO THE VANADIUM NITROGENASES
MALINAK, SM
DEMADIS, KD
COUCOUVANIS, D
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (11) : 3126 - 3133
[7] The first oxovanadium(V)-Thiolate complex, [VO(SCH2CH2)(3)N]
Nanda, KK
Sinn, E
Addison, AW
[J]. INORGANIC CHEMISTRY, 1996, 35 (01) : 1 - 2
[8] Pau R. N., 1991, Biology and biochemistry of nitrogen fixation., P37
[9] Rees D. C., 1993, ADV INORG CHEM, V40, P89
[10] Reactions of small molecules at transition metal sites: Studies relevant to nitrogenase, an organometallic enzyme
Richards, RL
[J]. COORDINATION CHEMISTRY REVIEWS, 1996, 154 : 83 - 97

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