Design, synthesis, application and recovery of a minimally fluorous diaryl diselenide for the catalysis of stannane-mediated radical chain reactions

被引：36

作者：

Crich, D ^{[1
]}

Hao, XL ^{[1
]}

Lucas, M ^{[1
]}

机构：

[1] Univ Illinois, Dept Chem, Chicago, IL 60607 USA

来源：

TETRAHEDRON | 1999年 / 55卷 / 50期

基金：

美国国家科学基金会;

关键词：

radicals and radical reactions; catalysis; selenium and compounds; fluorine and compounds;

D O I：

10.1016/S0040-4020(99)00902-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis of a minimally fluorous (52% F) diaryl diselenide is described. On reduction in situ with tributylstannane this diselenide provides a fluorous selenol which is effective in inhibiting a range of stannane-mediated radical rearrangements, including a cyclopropylcarbinyl ring opening. A method for the recovery of the fluorous diselenide involving continuous extraction in a modified, cooled continuous extractor is described. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

收藏

页码：14261 / 14268

页数：8

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