Selective colorimetric sensing for F- by a cleft-shaped anion receptor containing amide and hydroxyl as recognition units

被引：63

作者：

Bao, Xiaoping ^{[1
]}

Yu, Jinhua ^{[1
]}

Zhou, Yuhui ^{[2
]}

机构：

[1] Guizhou Univ, Minist Educ, Key Lab Green Pesticide & Agr Bioengn, Ctr Res & Dev Fine Chem, Guiyang 550025, Peoples R China

[2] Guizhou Univ, Dept Chem, Guiyang 550025, Peoples R China

来源：

SENSORS AND ACTUATORS B-CHEMICAL | 2009年 / 140卷 / 02期

关键词：

Anion binding; Calorimetric sensing; Amide; Hydroxyl; Hydrogen bond; FLUORIDE; SENSORS; THIOUREA;

D O I：

10.1016/j.snb.2009.04.056

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A simple cleft-shaped anion receptor 1 containing amide and hydroxyl as recognition units was synthesized and its anion recognition properties were investigated by naked-eye observation, UV-vis, fluorescence and (1)H NMR spectra. Receptor 1 could effectively recognize F(-) via multiple H-bonding interactions, along with visible color change and remarkable fluorescence enhancement. interestingly, reference compound 2 only containing amide groups did not display any interaction for all of the examined anions, including F(-). (C) 2009 Elsevier B.V. All rights reserved.

引用

页码：467 / 472

页数：6

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