Synthesis and photovoltaic properties of novel organic sensitizers containing indolo[1,2-f]phenanthridine for solar cell

被引:62
作者
Baik, Chul [1 ]
Kim, Duckhyun [1 ]
Kang, Moon-Sung [2 ]
Song, Kihyung [3 ]
Kang, Sang Ook [1 ]
Ko, Jaejung [1 ]
机构
[1] Korea Univ, Dept Adv Mat Chem, Jochiwon 339700, Chungnam, South Korea
[2] Samsung Adv Inst Technol, Energy & Environm Lab, Yongin 446712, South Korea
[3] Korea Natl Univ Educ, Dept Chem Educ, Cheongwon 363791, Chungbuk, South Korea
关键词
Indolo[1,2-f]phenanthridine; Organic dye; Dye-sensitized solar cell; DSSCs; HIGHLY-EFFICIENT; CONVERSION EFFICIENCY; MEROCYANINE DYES; COUMARIN DYES; DESIGN; ELECTROLYTE;
D O I
10.1016/j.tet.2009.04.077
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Organic dyes containing indolo[1,2-f]phenanthridine unit are a promising new class of sensitizers for dye-sensitized solar cells, as a result of their broad and intense visible absorptions. Under standard global AM 1.5 solar condition, the JK-61 sensitized cell gave a short circuit photocurrent density (J(sc)) of 15.81 mA cm(-2), an open circuit voltage (V-oc) of 0.73 V, a fill factor of 0.72, corresponding to an overall conversion efficiency of 8.34%. (C) 2009 Published by Elsevier Ltd.
引用
收藏
页码:5302 / 5307
页数:6
相关论文
共 38 条
[1]   Voltammetric determination of the reversible redox potential for the oxidation of the highly surface active polypyridyl ruthenium photovoltaic sensitizer cis-Ru(II)(dcbpy)2(NCS)2 [J].
Bond, AM ;
Deacon, GB ;
Howitt, J ;
MacFarlane, DR ;
Spiccia, L ;
Wolfbauer, G .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1999, 146 (02) :648-656
[2]   Low-band-gap conjugated polymers based on thiophene, benzothiadiazole, and benzobis(thiadiazole) [J].
Bundgaard, E ;
Krebs, FC .
MACROMOLECULES, 2006, 39 (08) :2823-2831
[3]   Stepwise Cosensitization of Nanocrystalline TiO2 Films Utilizing Al2O3 Layers in Dye-Sensitized Solar Cells [J].
Choi, Hyunbong ;
Kim, Sanghoon ;
Kang, Sang Ook ;
Ko, Jaejung ;
Kang, Moon-Sung ;
Clifford, John N. ;
Forneli, Amparo ;
Palomares, Emilio ;
Nazeeruddin, Mohammad K. ;
Graetzel, Michael .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (43) :8259-8263
[4]   Highly efficient and thermally stable organic sensitizers for solvent-free dye-sensitized solar cells [J].
Choi, Hyunbong ;
Baik, Chul ;
Kang, Sang Ook ;
Ko, Jaejung ;
Kang, Moon-Sung ;
Nazeeruddin, Md. K. ;
Graetzel, Michael .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (02) :327-330
[5]   Novel organic dyes containing bis-dimethylfluorenyl amino benzo[b]thiophene for highly efficient dye-sensitized solar cell [J].
Choi, Hyunbong ;
Lee, Jae Kwan ;
Song, Kihyung ;
Kang, Sang Ook ;
Ko, Jaejung .
TETRAHEDRON, 2007, 63 (15) :3115-3121
[6]   Photoelectrochemical cells [J].
Grätzel, M .
NATURE, 2001, 414 (6861) :338-344
[7]   LIGHT-INDUCED REDOX REACTIONS IN NANOCRYSTALLINE SYSTEMS [J].
HAGFELDT, A ;
GRATZEL, M .
CHEMICAL REVIEWS, 1995, 95 (01) :49-68
[8]   Novel conjugated organic dyes for efficient dye-sensitized solar cells [J].
Hara, K ;
Sato, T ;
Katoh, R ;
Furube, A ;
Yoshihara, T ;
Murai, M ;
Kurashige, M ;
Ito, S ;
Shinpo, A ;
Suga, S ;
Arakawa, H .
ADVANCED FUNCTIONAL MATERIALS, 2005, 15 (02) :246-252
[9]   Design of new coumarin dyes having thiophene moieties for highly efficient organic-dye-sensitized solar cells [J].
Hara, K ;
Kurashige, M ;
Dan-oh, Y ;
Kasada, C ;
Shinpo, A ;
Suga, S ;
Sayama, K ;
Arakawa, H .
NEW JOURNAL OF CHEMISTRY, 2003, 27 (05) :783-785
[10]   Novel polyene dyes for highly efficient dye-sensitized solar cells [J].
Hara, K ;
Kurashige, M ;
Ito, S ;
Shinpo, A ;
Suga, S ;
Sayama, K ;
Arakawa, H .
CHEMICAL COMMUNICATIONS, 2003, (02) :252-253