Hydrothermal synthesis and characterization of a two-dimensional nickel(II) complex containing benzenehexacarboxylic acid (mellitic acid)

被引：36

作者：

Kumagai, H

Oka, Y

Akita-Tanaka, M

Inoue, K

机构：

[1] IMS, Okazaki, Aichi 4448585, Japan

[2] Grad Univ Adv Studies, Dept Struct Mol Sci, Okazaki, Aichi 4448585, Japan

来源：

INORGANICA CHIMICA ACTA | 2002年 / 332卷

基金：

日本学术振兴会;

关键词：

nickel complexes; crystal structures; mellitate complexes; coordination polymer;

D O I：

10.1016/S0020-1693(01)00786-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The hydrothermal synthesis, single crystal X-ray structure and magnetic properties of a two-dimensional (2-D) coordination polymer, [Ni-4(C-6(COO)(6))(OH)(2)(H2O)(6)] (1), is described. Complex 1 consists of dimer motifs of pseudo octahedral NiO6 linked through mu3-OH to generate one-dimensional (1-D) chains which are further bridged by the mellitate ligands to form non interpenetrated undulating sheet structure. The sheets are further connected by hydrogen bonding interaction to yield a three-dimensional (3-D) structure. The temperature dependence of magnetic susceptibilities revealed the presence of antiferromagnetic interaction between nickel centers. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

收藏

页码：176 / 180

页数：5

相关论文

共 30 条

[1] Tailored porous materials [J].

Barton, TJ ;

Bull, LM ;

Klemperer, WG ;

Loy, DA ;

McEnaney, B ;

Misono, M ;

Monson, PA ;

Pez, G ;

Scherer, GW ;

Vartuli, JC ;

Yaghi, OM .

CHEMISTRY OF MATERIALS, 1999, 11 (10) :2633-2656

[2] Selective formation of rectangular grid coordination polymers with grid dimensions 10 x 15, 10 x 20 and 15 x 20 Å [J].

Biradha, K ;

Fujita, M .

CHEMICAL COMMUNICATIONS, 2001, (01) :15-16

[3]

Cheetham AK, 1999, ANGEW CHEM INT EDIT, V38, P3268, DOI 10.1002/(SICI)1521-3773(19991115)38:22<3268::AID-ANIE3268>3.0.CO

[4]

2-U

[5] The inorganic chemistry of solids: where have we come from? Where are we going? [J].

Day, P .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (20) :3483-3488

[6] THE RIBBON STRUCTURE OF CATENA-(MU-4-(DIHYDROGEN MELLITATO)-BIS[BIS(OXAMIDE OXIME-N,N')NICKEL(II)]) TETRAHYDRATE, [NI2(C12H2O12)(C2H6N4O2)2].4H2O [J].

ENDRES, H ;

KNIESZNER, A .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1984, 40 (MAY) :770-772

[7] Self-assembly of [2]catenanes containing metals in their backbones [J].

Fujita, M .

ACCOUNTS OF CHEMICAL RESEARCH, 1999, 32 (01) :53-61

[8] Syntheses and structures of Group 1 mellitate compounds, K6[C6(COO)6]•8H2O and Cs5[C6(COO)6H]•7H2O [J].

Harnisch, JA ;

Thomas, LM ;

Guzei, IA ;

Angelici, RJ .

INORGANICA CHIMICA ACTA, 1999, 286 (02) :207-214

[9] Chemistry and physics of supramolecular magnetic materials [J].

Kahn, O .

ACCOUNTS OF CHEMICAL RESEARCH, 2000, 33 (10) :647-657

[10] Rational design of a novel intercalation system. Layer-gap control of crystalline coordination polymers, {[Cu(CA)(H2O)(m)](G)}(n) (m=2,G=2,5-dimethylpyrazine and phenazine; m=1,G=1,2,3,4,6,7,8,9-octahydrophenazine) [J].

Kawata, S ;

Kitagawa, S ;

Kumagai, H ;

Kudo, C ;

Kamesaki, H ;

Ishiyama, T ;

Suzuki, R ;

Kondo, M ;

Katada, M .

INORGANIC CHEMISTRY, 1996, 35 (15) :4449-4461