Synthesis, characterization and cell performance of inverse spinel electrode materials for lithium secondary batteries

被引：95

作者：

Fey, GTK ^{[1
]}

Huang, DL ^{[1
]}

机构：

[1] Natl Cent Univ, Dept Chem Engn, Chungli 32054, Taiwan

来源：

ELECTROCHIMICA ACTA | 1999年 / 45卷 / 1-2期

关键词：

LiNiVO4; LiCoVO4; high-voltage cathode materials; inverse spinel; anode materials; lithium secondary batteries; XRD; FTIR; cyclic voltammetry;

D O I：

10.1016/S0013-4686(99)00212-1

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The preparation methods, materials' characterization, and electrochemical properties of inverse spinel materials, such as LiNiVO4, LiCoVO4, and LiNiyCo1-yVO4, are reviewed. The preparation methods include conventional ceramic sintering, solution co-precipitation, sol-gel, and hydrothermal methods. Recent structural results for these materials obtained from XRD, IR, Raman, Li-7 NMR, EXAFS, and XANES analyses are presented. Their electrochemical properties in terms of cyclic voltammetry, electrical conductivity, cathode and anode performance were also discussed. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：295 / 314

页数：20

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