Determination of resistance to coking in the steam reforming of hydrocarbons

被引:10
作者
Borowiecki, T [1 ]
Denis, A
Grzegorczyk, W
Golebiowski, A
机构
[1] Marie Curie Sklodowska Univ, Fac Chem, PL-20031 Lublin, Poland
[2] Inst Fertilizers, PL-24100 Pulawy, Poland
来源
REACTION KINETICS AND CATALYSIS LETTERS | 2002年 / 77卷 / 01期
关键词
steam reforming of hydrocarbons; TPReaction; Ni-Mo/Al2O3; coking;
D O I
10.1023/A:1020364424677
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
For a long time the microbalance reactor has played an important role in catalyst deactivation studies, but it has a number of limitations. The initial temperatures of coking of Ni and Ni-Mo catalysts in the temperature-programmed reaction (TPReaction) of n-butane with steam are compared with the results of coking rates obtained by the traditional thermogravimetric method. The investigations show good agreement of the results.
引用
收藏
页码:163 / 172
页数:10
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