Stereoselective radical reactions of some tartaric and glyceric acid derivatives

被引:8
作者
Barros, MT
Maycock, CD [1 ]
Ventura, MR
机构
[1] Univ Nova Lisboa, Fac Ciencias & Tecnol, Dept Quim, P-2825114 Monte De Caparica, Portugal
[2] Univ Nova Lisboa, Inst Tecnol Quim & Biol, P-2780156 Oeiras, Portugal
关键词
D O I
10.1021/ol025880w
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
[GRAPHIC] Free radicals generated by the decarboxylation of dimethoxydioxanecarboxylic acids derived from L-(+)-tartaric acid and L-glyceric acid added to some maleimides and acrylates with high stereoselectivity. This method provides easy access to some chiral building blocks.
引用
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页码:2035 / 2038
页数:4
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