Diammonium titanium pentafluoride, (NH4)2TiF5, containing Ti3+

被引：6

作者：

Dadachov, M ^{[1
]}

Eriksson, L ^{[1
]}

机构：

[1] Stockholm Univ, Arrhenius Lab, Div Struct Chem, S-10691 Stockholm, Sweden

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1999年 / 55卷

关键词：

D O I：

10.1107/S0108270199008689

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Single crystals of the title compound have been synthesized by low-temperature hydrothermal treatment of titanium isopropoxide in the presence of hydrofluoric acid and ethylenediamine. The compound consists of parallel infinite chains of trans-corner-connected TiF6 octahedra along the b axis, separated from each other by NH4+ ions. The Ti atoms lie on inversion centres and the ammonium ions on mirror planes.

引用

页码：1739 / 1741

页数：3

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