Synthesis crystal structure and magnetic properties of the trinuclear nickel(II) complex bis[(μ-thiocyanato-N)bis(μ-pyridazine-N1,N2)bis(thiocyanato-N)(pyridazine-N1)nickel(II)- N,N1,N1′]nickel(II)

被引：45

作者：

Cano, J

De Munno, G ^{[1
]}

Lloret, F

Julve, M

机构：

[1] Univ Calabria, Dipartimento Chim, I-87030 Cosenza, Italy

[2] Univ Valencia, Fac Quim, Dept Quim Inorgan, E-46100 Valencia, Spain

来源：

INORGANIC CHEMISTRY | 2000年 / 39卷 / 07期

关键词：

D O I：

10.1021/ic991219l

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Unusual single N-bridging thiocyanato and double pyridazine (pdz) bridges occur in the linear trinuclear nickel(II) complex of formula [Ni-3(pdz)(6)(NCS)(6)]. The compound exhibits a quasi Curie law behavior, the antiferromagnetic coupling through the double 1,2-diazine links being nearly compensated by the ferromagnetic exchange through the single N-bridging thiocyanato.

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页码：1611 / +

页数：5

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