Mixed peroxides from the chloroperoxidase-catalyzed oxidation of conjugated dienoic esters with a trisubstituted terminal double bond

被引：9

作者：

Bougioukou, DJ ^{[1
]}

Smonou, I ^{[1
]}

机构：

[1] Univ Crete, Dept Chem, Iraklion 71409, Crete, Greece

来源：

TETRAHEDRON LETTERS | 2002年 / 43卷 / 25期

关键词：

chloroperoxidase; oxidation; dienoic esters; mixed peroxides; epoxidation;

D O I：

10.1016/S0040-4039(02)00819-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The chloroperoxidase (CPO)-catalyzed oxidations of conjugated dienoic esters with a trisubstituted terminal double bond were studied by using tert-butyl hydroperoxide as the terminal oxidant. Most of the substrates gave disubstituted mixed peroxides as the major products. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：4511 / 4514

页数：4

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