Solid solutions TbFe1-xAlxO3 (0<=x<=1): Structure and magnetic behaviour

被引:21
作者
Bombik, A
Lesniewska, B
Mayer, J
Oles, A
Pacyna, AW
Przewoznik, J
机构
[1] H NIEWODNICZANSKI INST NUCL PHYS,PL-31342 KRAKOW,POLAND
[2] ACAD MIN & MET,FAC PHYS & NUCL TECHNIQUES,PL-30059 KRAKOW,POLAND
关键词
rare-earth orthoferrites; magnetic vacancies; magnetic susceptibility; compensation point; crystal structure; thermal analysis;
D O I
10.1016/S0304-8853(96)00673-7
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Magnetic X-ray, neutron diffraction and DSC measurements for a solid solution of the TbFe1-xAlxO3 system have been carried out, The results obtained indicate an essential role for Al substitutions on the magnetic behaviour of the compounds examined. For low Al concentration, a radical reduction of magnetic susceptibility of the compounds has been observed. The increase in Al concentration (x = 0.4-0.7) generates a compensation temperature (similar to 35 K) in the system, This effect is responsible for the change in the type of Tb-Fe coupling (from ferromagnetic to antiferromagnetic).
引用
收藏
页码:139 / 148
页数:10
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