Bifunctional palladium-basic zeolites as catalyst for Suzuki reaction

被引:96
作者
Corma, A [1 ]
García, H [1 ]
Leyva, A [1 ]
机构
[1] CSIC, Inst Tecnol Quim, Valencia 46022, Spain
关键词
basic zeolites; biphenyl formation; Pd2+-zeolites; bifunctional zeolite catalyst; Suzuki reaction;
D O I
10.1016/S0926-860X(02)00285-5
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Suzuki-type C-C forming reaction of phenyl bromide with pherylboronic acid to give biphenyl has been performed for the first time using Pd-containing basic zeolites as heterogeneous catalyst. In toluene as solvent, no Pd leaching was observed and the solids could be reused after water washings with only a minor decrease in the catalytic activity of the zeolite. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:179 / 185
页数:7
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