The status of PCB radiation chemistry research; prospects for waste treatment in nonpolar solvents and soils

被引：19

作者：

Curry, RD

Mincher, BJ

机构：

[1] Univ Missouri, Dept Elect Engn, Columbia, MO 65211 USA

[2] Idaho Natl Engn & Environm Lab, Idaho Falls, ID 83404 USA

来源：

RADIATION PHYSICS AND CHEMISTRY | 1999年 / 56卷 / 04期

关键词：

D O I：

10.1016/S0969-806X(99)00336-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

This paper presents a review of PCB radiolysis in oil, polar and nonpolar solvents and soil. The origins of PCB radiolysis research in alkaline isopropanol are discussed, and contrasted with radiolysis in neutral isopropanol and nonpolar solutions. Micellar solution chemistry is presented. Additionally, new applications of soil PCB radiolysis will be discussed and the effect of soil on the chemistry shown. The applicability of the extraction of PCBs from soil followed by the floatation of the solvent and subsequent radiolysis of the PCB in the floatant are reported, along with radiolysis of PCB in soil matrices. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：493 / 502

页数：10

共 38 条

[1] CHEMICAL-REACTION RATES OF QUASIFREE ELECTRONS IN NONPOLAR LIQUIDS .2. [J].