Polymer-Assisted Direct Deposition of Uniform Carbon Nanotube Bundle Networks for High Performance Transparent Electrodes

被引:145
作者
Hellstrom, Sondra L. [2 ]
Lee, Hang Woo [1 ]
Bao, Zhenan [1 ]
机构
[1] Stanford Univ, Dept Chem Engn, Stanford, CA 94305 USA
[2] Stanford Univ, Dept Appl Phys, Stanford, CA 94305 USA
关键词
transparent conductors; nanotubes; composites; solution processed; solar cells; LIGHT-EMITTING-DIODES; PHOTOVOLTAIC DEVICES; TRANSPORT-PROPERTIES; CONDUCTIVE COATINGS; THIN-FILMS; FABRICATION; SPECTROSCOPY; TEMPERATURE;
D O I
10.1021/nn9002456
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Flexible transparent electrodes are crucial for touch screen, flat panel display, and solar cell technologies. While carbon nanotube network electrodes show promise, characteristically poor dispersion properties have limited their practicality. We report that addition of small amounts of conjugated polymer to nanotube dispersions enables straightforward fabrication of uniform network electrodes by spin-coating and simultaneous tuning of parameters such as bundle size and density. After treatment in thionyl chloride, electrodes have sheet resistances competitive with other reported carbon nanotube based transparent electrodes to date.
引用
收藏
页码:1423 / 1430
页数:8
相关论文
共 44 条
[1]   Reversibility, dopant desorption, and tunneling in the temperature-dependent conductivity of type-separated, conductive carbon nanotube networks [J].
Barnes, Teresa M. ;
Blackburn, Jeffrey L. ;
van de Lagemaat, Jao ;
Coutts, Timothy J. ;
Heben, Michael J. .
ACS NANO, 2008, 2 (09) :1968-1976
[2]   Evaluation of solution-processed reduced graphene oxide films as transparent conductors [J].
Becerril, Hdctor A. ;
Mao, Jie ;
Liu, Zunfeng ;
Stoltenberg, Randall M. ;
Bao, Zhenan ;
Chen, Yongsheng .
ACS NANO, 2008, 2 (03) :463-470
[3]   Transparent conductive single-walled carbon nanotube networks with precisely tunable ratios of semiconducting and metallic nanotubes [J].
Blackburn, Jeffrey L. ;
Barnes, Teresa M. ;
Beard, Matthew C. ;
Kim, Yong-Hyun ;
Tenent, Robert C. ;
McDonald, Timothy J. ;
To, Bobby ;
Coutts, Timothy J. ;
Heben, Michael J. .
ACS NANO, 2008, 2 (06) :1266-1274
[4]   A mechanical assessment of flexible optoelectronic devices [J].
Chen, Z ;
Cotterell, B ;
Wang, W ;
Guenther, E ;
Chua, SJ .
THIN SOLID FILMS, 2001, 394 (1-2) :201-205
[5]   Continuous and Scalable Fabrication of Transparent Conducting Carbon Nanotube Films [J].
Dan, Budhadipta ;
Irvin, Glen C. ;
Pasquali, Matteo .
ACS NANO, 2009, 3 (04) :835-843
[6]   Transparent, Flexible, and Highly Conductive Thin Films Based on Polymer - Nanotube Composites [J].
De, Sukanta ;
Lyons, Philip E. ;
Sorel, Sophie ;
Doherty, Evelyn M. ;
King, Paul J. ;
Blau, Werner J. ;
Nirmalraj, Peter N. ;
Boland, John J. ;
Scardaci, Vittorio ;
Joimel, Jerome ;
Coleman, Jonathan N. .
ACS NANO, 2009, 3 (03) :714-720
[7]   Effect of SOCl2 treatment on electrical and mechanical properties of single-wall carbon nanotube networks [J].
Dettlaff-Weglikowska, U ;
Skákalová, V ;
Graupner, R ;
Jhang, SH ;
Kim, BH ;
Lee, HJ ;
Ley, L ;
Park, YW ;
Berber, S ;
Tománek, D ;
Roth, S .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (14) :5125-5131
[8]   Magnetically aligned single wall carbon nanotube films: Preferred orientation and anisotropic transport properties [J].
Fischer, JE ;
Zhou, W ;
Vavro, J ;
Llaguno, MC ;
Guthy, C ;
Haggenmueller, R ;
Casavant, MJ ;
Walters, DE ;
Smalley, RE .
JOURNAL OF APPLIED PHYSICS, 2003, 93 (04) :2157-2163
[9]   Crossed nanotube junctions [J].
Fuhrer, MS ;
Nygård, J ;
Shih, L ;
Forero, M ;
Yoon, YG ;
Mazzoni, MSC ;
Choi, HJ ;
Ihm, J ;
Louie, SG ;
Zettl, A ;
McEuen, PL .
SCIENCE, 2000, 288 (5465) :494-497
[10]   Effect of carbon nanotube types in fabricating flexible transparent conducting films [J].
Geng, Hong-Zhang ;
Lee, Dae Sik ;
Kim, Ki Kang ;
Kim, Sung Jin ;
Bae, Jung Jun ;
Lee, Young Hee .
JOURNAL OF THE KOREAN PHYSICAL SOCIETY, 2008, 53 (02) :979-985