Use of indium hydride (Cl2InH) for chemoselective reduction of the carbon-carbon double bond in conjugated alkenes

被引：33

作者：

Ranu, BC ^{[1
]}

Samanta, S ^{[1
]}

机构：

[1] Indian Assoc Cultivat Sci, Dept Organ Chem, Kolkata 700032, W Bengal, India

来源：

TETRAHEDRON LETTERS | 2002年 / 43卷 / 41期

关键词：

indium chloride; sodium borohydride; reduction; conjugated; alkene; C = C bond;

D O I：

10.1016/S0040-4039(02)01668-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Indium hydride (Cl2InH) generated in situ from a combination of a catalytic amount of indium(III) chloride and sodium borohydride selectively reduces the carbon-carbon double bond in conjugated alkenes such as alpha,alpha-dicyano olefins, alpha, beta-unsaturated nitriles, cyano esters, cyanophosphonate, diesters and ketones. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：7405 / 7407

页数：3

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