High-surface-area oxides obtained by an activated carbon route

被引:150
作者
Schwickardi, M [1 ]
Johann, T [1 ]
Schmidt, W [1 ]
Schüth, F [1 ]
机构
[1] Max Planck Inst Kohlenforsch, D-45470 Mulheim, Germany
关键词
D O I
10.1021/cm0211857
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
High-surface-area materials of various different compositions can be synthesized by a route involving impregnation of activated carbons with concentrated metal salt solutions and subsequent calcination to burn off the carbon material. This route allows the synthesis of a wide variety of different metal oxides, either as defined phases, if suitably chosen amounts of precursor salts are used, or as amorphous or partially crystalline multinary mixed-metal oxides. Typically, surface areas in the range between 50 and 200 m(2)/g are accessible, and in addition to crystalline binary oxides, several high-surface-area spinels and perovskites can also be prepared.
引用
收藏
页码:3913 / 3919
页数:7
相关论文
共 21 条
[1]   Tailored porous materials [J].
Barton, TJ ;
Bull, LM ;
Klemperer, WG ;
Loy, DA ;
McEnaney, B ;
Misono, M ;
Monson, PA ;
Pez, G ;
Scherer, GW ;
Vartuli, JC ;
Yaghi, OM .
CHEMISTRY OF MATERIALS, 1999, 11 (10) :2633-2656
[2]   An investigation into the preparation of high surface area zirconia [J].
Chuah, GK .
CATALYSIS TODAY, 1999, 49 (1-3) :131-139
[3]   Influence of the sol-gel processing method on the structure and the porous texture of nondoped aluminas [J].
Elaloui, E ;
Pierre, AC ;
Pajonk, GM .
JOURNAL OF CATALYSIS, 1997, 166 (02) :340-346
[4]   Nanoscale casting using supercritical fluid [J].
Fukushima, Y ;
Wakayama, H .
JOURNAL OF PHYSICAL CHEMISTRY B, 1999, 103 (16) :3062-3064
[5]  
Klein J, 1998, ANGEW CHEM INT EDIT, V37, P3369, DOI 10.1002/(SICI)1521-3773(19981231)37:24<3369::AID-ANIE3369>3.0.CO
[6]  
2-H
[7]   Alumina supported, perovskite oxide based catalytic materials and their auto-exhaust application [J].
Labhsetwar, NK ;
Watanabe, A ;
Biniwale, RB ;
Kumar, R ;
Mitsuhashi, T .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2001, 33 (02) :165-173
[8]   Nanosized zeolite crystals - convenient control of crystal size distribution by confined space synthesis [J].
Madsen, C ;
Jacobsen, CJH .
CHEMICAL COMMUNICATIONS, 1999, (08) :673-674
[9]   PREPARATION AND CHARACTERIZATION OF MICROPOROUS METAL-OXIDES [J].
MAIER, WF ;
TILGNER, IC ;
WIEDORN, M ;
KO, HC .
ADVANCED MATERIALS, 1993, 5 (10) :726-730
[10]   Titanium dioxide nanoparticles produced in water-in-oil emulsion [J].
Mori, Y ;
Okastu, Y ;
Tsujimoto, Y .
JOURNAL OF NANOPARTICLE RESEARCH, 2001, 3 (2-3) :219-225