Measurement of SO2 solubility in ionic liquids

被引：307

作者：

Anderson, Jessica L. ^{[1
]}

Dixon, JaNeille K. ^{[1
]}

Maginn, Edward J. ^{[1
]}

Brennecke, Joan F. ^{[1
]}

机构：

[1] Univ Notre Dame, Dept Chem & Biomol Engn, Notre Dame, IN 46556 USA

来源：

JOURNAL OF PHYSICAL CHEMISTRY B | 2006年 / 110卷 / 31期

关键词：

D O I：

10.1021/jp063547u

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Measurements of the solubility of sulfur dioxide (SO2) in the ionic liquids 1-n-hexyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([hmim][Tf2N]) and 1-n-hexyl-3-methylpyridinium bis(trifluoromethylsulfonyl) imide ([hmpy][Tf2N]) at temperatures from 25 to 60 degrees C and pressures up to 4 bar indicate that large amounts (up to 85 mol %) of SO2 dissolve in ionic liquids by simple physical absorption.

引用

页码：15059 / 15062

页数：4

共 33 条

[1] Anthony JL, 2005, J PHYS CHEM B, V109, P6366, DOI [10.1021/jp046404l, 10.1021/jp0464041]
[2] Solubilities and thermodynamic properties of gases in the ionic liquid 1-n-butyl-3-methylimidazolium hexafluorophosphate
Anthony, JL
Maginn, EJ
Brennecke, JF
[J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2002, 106 (29) : 7315 - 7320
[3] ASTARITA S, 1983, GAS TREATING CHEM SO, P493
[4] Examination of the potential of ionic liquids for gas separations
Baltus, RE
Counce, RM
Culbertson, BH
Luo, HM
DePaoli, DW
Dai, S
Duckworth, DC
[J]. SEPARATION SCIENCE AND TECHNOLOGY, 2005, 40 (1-3) : 525 - 541
[5] Low-pressure solubility of carbon dioxide in room-temperature ionic liquids measured with a quartz crystal microbalance
Baltus, RE
Culbertson, BH
Dai, S
Luo, HM
DePaoli, DW
[J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (02) : 721 - 727
[6] CO2 capture by a task-specific ionic liquid
Bates, ED
Mayton, RD
Ntai, I
Davis, JH
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (06) : 926 - 927
[7] High-pressure phase behavior of ionic liquid/CO2 systems
Blanchard, LA
Gu, ZY
Brennecke, JF
[J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2001, 105 (12) : 2437 - 2444
[8] Why is CO2 so soluble in imidazolium-based ionic liquids?
Cadena, C
Anthony, JL
Shah, JK
Morrow, TI
Brennecke, JF
Maginn, EJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (16) : 5300 - 5308
[9] Cammarata L, 2001, PHYS CHEM CHEM PHYS, V3, P5192, DOI 10.1039/b106900d
[10] Gas solubilities in room-temperature ionic liquids
Camper, D
Scovazzo, P
Koval, C
Noble, R
[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2004, 43 (12) : 3049 - 3054

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