Luminescent metal-organic frameworks

被引：4662

作者：

Allendorf, M. D. ^{[1
]}

Bauer, C. A. ^{[2
]}

Bhakta, R. K. ^{[1
]}

Houk, R. J. T. ^{[1
]}

机构：

[1] Sandia Natl Labs, Livermore, CA 94550 USA

[2] Univ Calif Los Angeles, Dept Chem & Biochem, Los Angeles, CA 90095 USA

来源：

CHEMICAL SOCIETY REVIEWS | 2009年 / 38卷 / 05期

基金：

美国国家科学基金会;

关键词：

BACTERIAL SPORE DETECTION; 3D COORDINATION POLYMERS; CRYSTAL-STRUCTURES; MIXED-LIGANDS; HYDROTHERMAL SYNTHESIS; SUPRAMOLECULAR FRAMEWORKS; INTERCHAIN INTERACTIONS; EXCIPLEX FLUORESCENCE; TRIMETALLIC CLUSTERS; LANTHANIDE COMPLEXES;

D O I：

10.1039/b802352m

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Metal-organic frameworks (MOFs) display a wide range of luminescent behaviors resulting from the multifaceted nature of their structure. In this critical review we discuss the origins of MOF luminosity, which include the linker, the coordinated metal ions, antenna effects, excimer and exciplex formation, and guest molecules. The literature describing these effects is comprehensively surveyed, including a categorization of each report according to the type of luminescence observed. Finally, we discuss potential applications of luminescent MOFs. This review will be of interest to researchers and synthetic chemists attempting to design luminescent MOFs, and those engaged in the extension of MOFs to applications such as chemical, biological, and radiation detection, medical imaging, and electro-optical devices (141 references).

引用

页码：1330 / 1352

页数：23

共 144 条

[1]

[Anonymous], 1982, PHYS CHEM

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