One-pot desilylation/dimerization of ethynyl- and butadiynyltrimethylsilanes. Synthesis of tetrayne-linked dehydrobenzoannulenes.

被引：68

作者：

Haley, MM

Bell, ML

Brand, SC

Kimball, DB

Pak, JJ

Wan, WB

机构：

[1] Department of Chemistry, University of Oregon, Eugene

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 43期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/S0040-4039(97)01796-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Addition of K2CO3 to standard Eglinton coupling conditions effects a one-pot desilylation/dimerization reaction of alkynyltrimethylsilanes. Use of this procedure on substituted phenylbutadiynylsilanes ultimately leads to the formation of dehydrobenzoannulenes possessing an unprecedented number of acetylene linkers. (C) 1997 Elsevier Science Ltd.

引用

页码：7483 / 7486

页数：4

共 23 条

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