Polymerisation of cyanogen on graphite and graphite supported copper films

被引：11

作者：

Carley, AF

Chinn, M

Parkinson, CR

机构：

[1] Univ Wales Coll Cardiff, Dept Chem, Cardiff CF10 3TB, S Glam, Wales

[2] Dstl, Salisbury SP4 0JQ, Wilts, England

来源：

SURFACE SCIENCE | 2002年 / 517卷 / 1-3期

基金：

英国工程与自然科学研究理事会;

关键词：

X-ray photoelectron spectroscopy; chemisorption; surface chemical reaction; copper; carbon; cyanogen; polycrystalline thin films; metallic films;

D O I：

10.1016/S0039-6028(02)02099-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The adsorption of cyanogen, (CN)(2), on graphite and graphite-supported copper films has been investigated using Xray photoelectron spectroscopy. X-ray irradiation is shown to effect a polymerisation of condensed cyanogen overlayers, on both graphite and graphite supported copper film surfaces via a substrate-mediated secondary electron process. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：L563 / L567

页数：5

共 15 条

[1] AN EXAMINATION OF THE PRODUCTS FORMED ON REACTION OF HYDROGEN-CYANIDE AND CYANOGEN WITH COPPER, CHROMIUM (6+) AND COPPER CHROMIUM (6+) IMPREGNATED ACTIVATED CARBONS [J].