Spontaneous ring-collapsed alternating copolymerization of a homocyclic arsenic compound and phenylacetylene

被引：19

作者：

Umeyama, T ^{[1
]}

Naka, K ^{[1
]}

Chujo, Y ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Engn, Dept Polymer Chem, Nishikyo Ku, Katsura, Kyoto 6158510, Japan

来源：

MACROMOLECULES | 2004年 / 37卷 / 16期

关键词：

D O I：

10.1021/ma049113j

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Without any added catalyst or radical initiator at 25 degreesC, cyclo-(MeAs)(5) caused cleavage of the arsenic-arsenic bond spontaneously and copolymerized with phenylacetylene (PA) in chloroform to give a novel organoarsenic polymer having a methylarsine (MeAs) unit and a vinylbenzene unit alternating in the main chain, -[AsMe-CH=CPh](n)-. The rate of monomer consumption during the copolymerization was followed by a gas chromatography (GC) analysis, and the increase of the molecular weight of the resulting copolymer was monitored by GPC measurement. These analyses revealed that this system was step-reaction polymerization. The consumption of PA during the copolymerization with cyclo-(MeAs)(5) using AIBN was much faster as compared to the case without AIBN.

引用

页码：5952 / 5958

页数：7

共 29 条

[1] HYDROBORATION POLYMERIZATION .1. SYNTHESIS OF ORGANOBORON POLYMERS BY POLYADDITION BETWEEN DIENE AND MONOALKYLBORANE [J].