Thermal stability and reactions of CH2, CH3 and C2H5 species on the metal surfaces

被引：47

作者：

Solymosi, F ^{[1
]}

机构：

[1] HUNGARIAN ACAD SCI,REACT KINET RES GRP,H-6701 SZEGED,HUNGARY

来源：

CATALYSIS TODAY | 1996年 / 28卷 / 03期

关键词：

thermal stability of hydrocarbon fragments; metal surfaces;

D O I：

10.1016/0920-5861(95)00242-1

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The results obtained on thermal stability and reactions of CyHy hydrocarbon fragments on metal surfaces are discussed. CxHy species are produced by thermal and photo-induced dissociation of corresponding iodo compounds. Whereas CH3 and CH2 are mainly converted into CH4 on Pt metals at 140-180 K, they recombine readily to yield C-2 compounds on Ag and Cu surfaces. The C2H5 reacted to form C2H4 and C2H6 on metal surfaces at 160-230 K. Effects of additives and coadsorbed species on the reactions of CxHy moieties are also examined.

引用

页码：193 / 203

页数：11

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